- 产品参数
- 产品详情
- 产品评论
基本信息
| 产品名称 | 2-双环己基膦-2 ',6'-二异丙氧基联苯 |
|---|---|
| 英文名称 | 2-Dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl |
| 别名 | 二环己基(2',6'-二异丙氧基-[1,1'-联苯基]-2-基)膦；2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯；2-二环己基膦-2',6'-二异丙氧基联苯 |
| 英文别名 | RuPhos;Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine |
| 规格或纯度 | 98% |
| 运输条件 | 常规运输 |
| 生化机理 | ligand for Arylations Buchwald-Hartwig Cross Coupling Reaction Negishi Coupling Sonogashira Coupling Suzuki-Miyaura Coupling |
一般描述
大位阻膦配体，可用于氨基乙基三氟硼酸酯与缺电子芳基溴的钯催化交叉偶联反应
ligand for Arylations Buchwald-Hartwig Cross Coupling Reaction Negishi Coupling Sonogashira Coupling Suzuki-Miyaura Coupling
Bulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborates with electron-poor aryl bromides.
Application
Finds application in Buchwald-Hartwig cross coupling reactions, Arylation, Negishi and Sonogashira coupling reactions. A Ruphos-mediated Suzuki cross-coupling between (hetero)aryl bromides and secondary alkyltrifluoroborates is described using palladium catalysis. The Ruphos ligand showed superior properties as compared to S-Phos in this type of reaction. This method constitutes a valuable extension to current methods for the straightforward production of secondary-alkylated (hetero)aryl derivatives.
安全信息
| 标识符号 | GHS07 |
|---|---|
| 警示性声明 | P280 |
| 危害声明 | H413,H302,H312,H332 |
| WGK | 3 |
相关属性
| CAS编号 | 787618-22-8 |
|---|---|
| 敏感性 | 对空气敏感 |
| 熔点 | 123-126°C |
| 溶解性 | Insoluble in water. |
| 储存温度 | 充氩 |
| MDL号 | MFCD06798294 |
| 分子量 | 466.64 |
| 分子式 | C30H43O2P |
| 品牌 | 阿拉丁 |
| 法律信息 | Usage subject to US Patents 6307087 and 6395916. |
| PubChem CID | 16217985 |