| 产品名称 | 三氟乙酸甲酯(TFAM) |
|---|---|
| 英文名称 | Methyl trifluoroacetate |
| 别名 | 2,2,2-三氟乙酸甲酯 |
| 英文别名 | Trifluoroacetic Acid Methyl Ester |
| 应用 | 用于医药,农药中间体,有机合成砌块。 Methyl trifluoroacetate has been used as reagent for trifluoroacetylation of amines and amino acids. |
| 规格或纯度 | 99% |
| 运输条件 | 超低温冰袋运输 |
Methyl trifluoroacetate is a reagent for trifluoroacetylation of amines and amino acids.用于医药,农药中间体,有机合成砌块。 Methyl trifluoroacetate has been used as reagent for trifluoroacetylation of amines and amino acids.
Methyl trifluoroacetate is a reagent for trifluoroacetylation of amines and amino acids.
application:
Useful reagent for trifluoroacetylation of amines under mild conditions. In the presence of 1,1,3,3-TetramethylÂguanidine, has also been used for the N-acylation of amino acids. It is used as an intermediate in the synthesis of pharmaceutical and agricultural chemicals. The chemical reactions usually involve nucleophilic substitution of the ester and are useful for the preparation of trifluoroacylated compounds.
product description:
Methyl trifluoroacetate along with cesium fluoride or cesium chloride and CuI constitutes a valuable trifluoromethylating reagent for substituting aromatic (or heteroaromatic) iodides and bromides. Adsorption of methyl trifluoroacetate on amorphous silica has been investigated. Fragmentation mechanism of generation of metastable ions from methyl trifluoroacetate has been investigated by mass analyzed ion kinetic energy spectra and ab initio molecular orbital calculations.
| 标识符号 | GHS05, GHS02 |
|---|---|
| 信号词 | Danger |
| 警示性声明 | P305+P351+P338,P280,P210,P310 |
| 危害声明 | H314,H225 |
| 个人防护设备 | Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US) |
| WGK | 1 |
| 闪点(摄氏) | -7℃ |
| 闪点(华氏) | -4 °F |
| UN Number | 2924 |
| CAS编号 | 431-47-0 |
|---|---|
| 敏感性 | 对湿度敏感 |
| 折光率 | 1.2907 |
| 熔点 | -78°C |
| 沸点 | 43°C |
| 溶解性 | Not miscible or difficult to mix in water. |
| 储存温度 | -20°C储存,充氩 |
| Reaxys-RN | 1756070 |
| MDL号 | MFCD00000417 |
| 密度 | 1.29 |
| 分子量 | 128.05 |
| 分子式 | C3H3F3O2 |
| EC号 | 207-074-5 |
| 品牌 | 阿拉丁 |
| PubChem CID | 9893 |