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四丁基碘化铵 99%
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价格
¥29.00
货号
T103714-5g
市场价
¥0.00
品牌
阿拉丁
销量
0
库存量
100
CAS号
311-28-4
分子式
C16H36NI
分子量
369.37

基本信息

产品名称四丁基碘化铵
英文名称Tetrabutylammonium iodide
别名TBAI;碘化四丁基铵
英文别名TBAI;Tetra-n-butylammonium iodide
应用离子对色谱试剂,相转移催化剂,极谱分析试剂。有机合成。
规格或纯度99%
运输条件常规运输

一般描述

易吸湿。溶于水和乙醇,微溶于氯仿。有刺激性。水中溶解度<5%。 离子对色谱试剂,相转移催化剂,极谱分析试剂。有机合成。 Tetrabutylammonium iodide (TBAI) has been used as a catalyst in the following reactions: · Synthesis of O-benzyl-N-Boc-L-tyrosine benzyl ester from N-Boc-L-tyrosine. · Conversion of 8-fluoro-1-aminonaphthalene into 1-(8-fluoro-naphthalen-1-yl)piperazine hydrochloride. · Synthesis of 1-(2,4-dichlorophenyl)-5-(4-(4-iodobut-1-ynyl)phenyl)-4-methyl-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide from 4-(4-(1-(2,4-dichlorophenyl)-4-methyl-3-(piperidin-1-ylcarbamoyl)-1H-pyrazol-5-yl)phenyl)but-3-yn-1-yl methanesulfonate. Other reactions where TBAI can be used as a catalyst: · TBAI-tert-butyl hydroperoxide system can catalyze the conversion of α-methyl styrene derivatives into allylic sulfones by reacting with sulfonylhydrazides under metal-free conditions. · Palladium(0)-catalyzed cross-coupling between benzylic zinc bromides and aryl or alkenyl triflates. · Three-component coupling of amines, carbon dioxide, and halides to form ca


Tetrabutylammonium iodide (TBAI) has been used as a catalyst in the following reactions: · Synthesis of O-benzyl-N-Boc-L-tyrosine benzyl ester from N-Boc-L-tyrosine. · Conversion of 8-fluoro-1-aminonaphthalene into 1-(8-fluoro-naphthalen-1-yl)piperazine hydrochloride. · Synthesis of 1-(2,4-dichlorophenyl)-5-(4-(4-iodobut-1-ynyl)phenyl)-4-methyl-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide from 4-(4-(1-(2,4-dichlorophenyl)-4-methyl-3-(piperidin-1-ylcarbamoyl)-1H-pyrazol-5-yl)phenyl)but-3-yn-1-yl methanesulfonate. Other reactions where TBAI can be used as a catalyst: · TBAI-tert-butyl hydroperoxide system can catalyze the conversion of α-methyl styrene derivatives into allylic sulfones by reacting with sulfonylhydrazides under metal-free conditions. · Palladium(0)-catalyzed cross-coupling between benzylic zinc bromides and aryl or alkenyl triflates. · Three-component coupling of amines, carbon dioxide, and halides to form carbamates in the presence of cesium carbonate.

安全信息

标识符号 GHS07
警示性声明P261,P305+P351+P338
危害声明H315,H319,H335,H302
个人防护设备dust mask type N95 (US),Eyeshields,Gloves
WGK3

相关属性

CAS编号311-28-4
敏感性对湿度和光线敏感
熔点145-148°C
溶解性Soluble in water and methanol. Insoluble in benzene.
储存温度充氩
Reaxys-RN3916152
RTECSBS5450000
MDL号MFCD00011636
密度1.2
分子量369.37
分子式C16H36NI
EC号206-220-5
品牌阿拉丁
PubChem CID67553


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