苏科商城

有潮解性，易溶于稀盐酸，能溶于水、乙醇、丙酮和氢溴酸。 1、点滴测定钯、汞、铊和碘，提纯稀有气味，氯化钯试纸检验一氧化碳、检定钴。 2、催化剂，末端烯径（α-烯径）生成甲基酮的氧化催化。 3、通过Wacker反应，在水溶液中用空气作氧化剂，使烯径氧化成醛。 4、用于合成半导体含金属聚合体，该聚合体具有聚吡咯骨架，符合能量最小且接近平面。

Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Product class

PGM Solids, Chlorides

Reaction type

Cross Coupling Reactions with Arenes, CH-Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Oxidation

Chemical properties

Applications & references

Efficient oxidative carboxylation of benzylic C-H bonds via nondirected C(sp³)-H activation forming substituted 2-phenylacetic acid esters and derivatives starting from inexpensive, commercially available starting materials.

Reference: J. Am. Chem. Soc. 2012, 134, 9902 (DOI: 10.1021/ja3036459)

Efficient Palladium catalyzed hydroformylation of aryl and enol trifluoromethanesulfonates providing α,β-unsaturated aldehydes.

Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups.

Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)