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基本信息
| 产品名称 | 1-溴频哪酮 |
|---|---|
| 英文名称 | 1-Bromopinacolone |
| 别名 | 1-溴特己酮；1-溴-3,3-二甲基-2-丁酮；溴甲基叔丁基酮；溴甲基叔丁基甲酮 |
| 英文别名 | 1-Bromo-3,3-dimethyl-2-butanone;Bromomethyl tert-Butyl Ketone;1-Bromopinacolin |
| 应用 | It is the suitable reagent for the synthesis of a photolabile azido derivative of the kaurene oxidase inhibitor 1-(4- chlorophenyl)4,4-dimethyl-2-(1,2,4-triazol-1-yl) pentan-3-ol (paclobutrazol).It may be used as reagent in the synthesis of 2-t-butyl-6-benzoylimidazo[1,2-b]pyridazine. |
| 规格或纯度 | ≥97.0% |
| 运输条件 | 超低温冰袋运输 |
一般描述
It is an α-bromoketone-aldehyde.[1] Coupling of 1-bromopinacolone with various aldehyde electrophiles catalyzed by SmI2 has been reported.It acts as reversible competitive inhibitor for acetylcholinesterase, during hydrolysis of acetylcholine.It is the suitable reagent for the synthesis of a photolabile azido derivative of the kaurene oxidase inhibitor 1-(4- chlorophenyl)4,4-dimethyl-2-(1,2,4-triazol-1-yl) pentan-3-ol (paclobutrazol).It may be used as reagent in the synthesis of 2-t-butyl-6-benzoylimidazo[1,2-b]pyridazine.
1-Bromopinacolone is an α-bromoketone-aldehyde. Coupling of 1-bromopinacolone with various aldehyde electrophiles catalyzed by SmI2 has been reported. It acts as reversible competitive inhibitor for acetylcholinesterase, during hydrolysis of acetylcholine.
安全信息
| 标识符号 | GHS07 |
|---|---|
| 信号词 | Warning |
| 警示性声明 | P305+P351+P338,P280,P302+P352,P264,P337+P313,P362+P364,P332+P313 |
| 危害声明 | H315,H319 |
| 个人防护设备 | Eyeshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter |
| WGK | 3 |
| 闪点（摄氏） | 66°C(lit.) |
| 闪点（华氏） | 167 °F |
相关属性
| CAS编号 | 5469-26-1 |
|---|---|
| 敏感性 | 对空气&光&热敏感 |
| 折光率 | n20/D 1.466 |
| 熔点 | −10 °C |
| 沸点 | 188-194 °C |
| 溶解性 | Insoluble in water. |
| 储存温度 | 避光,-20°C储存,充氩 |
| Reaxys-RN | 506485 |
| RTECS | EL7010000 |
| MDL号 | MFCD00000206 |
| 密度 | 1.33 |
| 分子量 | 179.06 |
| 分子式 | C6H11BrO |
| 品牌 | 阿拉丁 |
| PubChem CID | 21642 |