苏科商城

不溶于水，溶于氯仿，微溶于二氯甲烷。

A catalyst for Suzuki and Stille couplings

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:

· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.

· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.

· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

用途：

用于C-C和C-N偶联反应的催化剂。

钯催化交叉偶联反应应用指南

Pd(dppf)Cl2可作为一种有效的钯催化剂用于以下反应：

具有高产率和选择性的仲烷基和正烷基格氏试剂的交叉偶联。

芳基硼酸酯与[11C]甲基碘形成官能化的[11C]甲苯衍生物的铃木偶联反应。

1,3,5-三溴苯与格氏试剂形成星形低聚噻吩的Kumada交叉偶联反应。

A catalyst for Suzuki and Stille couplings

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:

· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.

· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.

· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

Product class

M-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - Achiral

Reaction type

Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation

Chemical properties

Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)