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四氢呋喃硼烷络合物 1.0 M in THF,含5mmol硼氢化钠稳定剂
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价格
¥59.00
货号
B110263-25ml
市场价
¥0.00
品牌
阿拉丁
销量
0
库存量
100
CAS号
14044-65-6
分子式
BC4H11O
分子量
85.94

基本信息

产品名称四氢呋喃硼烷络合物
英文名称Borane tetrahydrofuran complex solution
别名四氢呋喃硼烷
英文别名Tetrahydrofuran Borane; Borane - Tetrahydrofuran Complex
应用常用于将聚酰胺纤维表面的酰胺基还原为仲胺。
规格或纯度1.0 M in THF,含5mmol硼氢化钠稳定剂
运输条件冰袋运输

一般描述

和水剧烈反应。对空气和湿度敏感。 常用于将聚酰胺纤维表面的酰胺基还原为仲胺。


Borane tetrahydrofuran complex (BH3-THF) is widely used as a reducing agent in organic synthesis. It is also used as a reagent in hydroboration reactions.
BH3-THF can be used as a reducing agent for the reduction of various functional groups such as carboxylic acids, aldehydes, ketones, esters, acid chlorides, nitriles, epoxides, amides, lactones, oximes, and imines into corresponding alcohols and amines. Grignard reagents, arylmercury, arylthalium, and allyl and propargyllithium compounds react with BH3−THF to give organoboranes, which can be oxidized to the corresponding alcohols, phenols, and 1,3-diols.
It can also be used:
To synthesize the chiral borane catalyst, which is used in the enantioselective halo-aldol reaction.
To prepare 9-unsubstituted acridines by reduction of corresponding acridones.
To reduce nylon surface amide groups to secondary amines.

安全信息

标识符号 GHS07, GHS02
信号词Danger
警示性声明P261,P223,P231+P232,P370+P378,P422,P210
危害声明H319,H335,H260,H225
个人防护设备Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
WGK3
闪点(摄氏)-17 °C
闪点(华氏)1.4 °F
UN Number3399

相关属性

CAS编号14044-65-6
敏感性对热、空气、湿度敏感
溶解性Miscible and reacts violently with water.
储存温度2-8°C储存,充氩
Reaxys-RN3668402
MDL号MFCD00012429
密度0.88
分子量85.94
分子式BC4H11O
品牌阿拉丁
PubChem CID11062302


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